I'd expect people would get 80fps in HL2 using a 256mb r9800pro instead of a 128mb, and using a faster processor. They probably run the game at lower settings as well.
The odds of you needing 8xAF are... well... low. Try lowering that, unless you definitely think you're seeing a huge difference with it. (possibly try AA?)
Additionally, I never really saw much of a purpose for vsync, so maybe try turning that off. Additionally, try benching yourself when you're past the airboat part. That mean old helicopter rapes most graphics cards through the water effects. :x