There are two levels at which to look at this problem.
Purely statistically, the mother donates one of two X chromosomes while the father donates either a X or Y chromosome. This second one determines the gender. It should be obvious why there is a 50/50 chance here.
Biologically, I'm pretty sure that chromosomes have no effect on the sperm cell carrying them, but it's quite possible that those carrying Y chromosomes are lighter, especially since Y chromosomes are much smaller than X chromosomes (
http://home.planet.nl/~gkorthof/images/XYchrom.jpg). I have no idea what other mechanisms affect the chance of selection at this level.