Why is libertarianism so infallible?

It is due to it being the application of political science. It does not permit failed policies to be continued fruitlessly year after year with idealistic fervour, it is next to impossible for anyone surrounded by fierce libertarian critics to continue clinging on to lies. It is a purely functional machine, lubricated with justice and fueled by free speech.

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You're still not being specific. If the person dumping toxic waste was just paid to and doesn't know what it is, then the police can just go up to him and order him not to do it.