Polish, Czech, Slav... similarities?

Good evening.

Purely as a hobby, i've decided that i'd like to pick up a European language (I already speak a couple Asian languages).
I initially wanted to learn Czech, but i was comparing populations that speak languages in Europe and found that Polish outnumbers it and that it also has a lot in common with slavic languages.

tl;dr:  Anyone who speaks Polish or Czech, or any combination of those Slav languages, are there similarities?  'ppreciate your comments.

what are the differences between Serb/Bosnian/Croatian other than Serbs use Cyrillic?